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Flowers For Sale

Flowers are associated in every culture with some values and symbolic importance. Almost all civilizations on the planet have made philosophical and religious references to the presence of flower on the planet. It is true that flowers are known for their vibrant colors and soothing aromas. In the ancient times flowers were a delicacy and luxury that only the royals could afford. People from all over the world relate different meanings to the flowers that are grown locally. The best flower shops in Abu Dhabi have the latest flower arrangements that bring out the best in people. Flowers are the jewelry that decorates the nature.

Importance of Flowers

Due to the historical and cultural values attached with flowers people are still fascinated by existence of this blessing in the physical realm. Flowers come in countless colors and shapes. However, in the modern times flowers are cultivated on a mass scale for the sake of their use in the decorative purposes. The retail buying industry of fresh flowers is continuously declining. People deem the profession of a florist to be filled with risks. However, with the help of little marketing flowers can be easily added to the daily mix.

Today, the flower industry is facing a massive competition from mass produced products that are filled with sugary substances. People are under the influence of marketing campaigns and advertising. The standalone flower shops do not have the massive budgets for flowers marketing. However, the people have a natural and inborn inclination towards fresh flowers that has kept the industry going till date. It is a great idea to support the fresh flowers industry as it is the one that brings people joy without causing them any harm.

The appearance of fresh flowers in the local culture has been reducing day by day. With the help of social media platforms people can start a movement to support the flower shops and help them get out of the deficit. The online flower delivery in Dubai has a better business acumen since customers can buy and send flowers with the help of websites and applications. There is a need to highlight the local flower business in the close proximity and help them become more stable and sustainable business models.


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Shorts and pants

Give your look a cool and causal touch to create a striking impact. Get the best out of your silhouette by mixing a tight short made of 100% guipure with a masculine cut blouse. You can also hit the bull’s-eye by unveiling some naked skin under a crop top and a high-waist palazzo-trousers. A homage to the ideal of feminine freedom initiated by Madmoiselle Coco Chanel.

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헬프캠프 | 캠핑을 돕다 | 초보자를 위한 캠핑장 추천

Northern United States truck sales

Because in the 1970s, Eastern vehicles like the Toyota Hiace as well as the Datsun Urvan, along with International styles based upon the Ford Transportation, Fiat Ducato, and also Bedford vehicles, have actually come to be well-liked as servile lorries for sales.

In North The United States there are actually lots of makers actually made through Roadtrek of Kitchener, Ontario.

Motorhome choose company

Campervan’s work with motor vehicles is actually normally much smaller than their motorhome equivalents. Contrastingly, motorhomes are going to deliver additional areas and also centers. Insurance policy along with campervan administration providers is actually frequently less expensive and also this leads to a total lesser complete hire expense.

Campervan control firms are actually dispersed throughout the entire world in reaction rentals has actually ended up being incredibly well-liked in New Zealand, along with lots of thinking about self-drive vacations to be actually one of the greatest means to the yard on country streets which are actually traffic-free matched up to those located in various other nations.

A motorhome hire firm (as well as the identical campervan hire organization) is actually a business that taps the services of confidentially had motorhomes (or even campervans) to clients. Motorhome hire is actually a kind of getaway rental.

Motorhome hire firms arose method started to take off along. A lot of UK motorhome managers have actually looked to get an added profit coming from their motorhome as a result of recession-related concerns such as task reductions.

In the UK, campervan monitoring providers accommodate festivity goers by delivering a remedy to the conventional storm as well as mud-soaked outdoor tents setting

Reservations come through the provider as well as the firm handles all the economic concerns and also insurance policy. The consumer is actually after that capable to pick up the motorhome coming from the manager as well as the proprietor is actually paid for a charge.

A motorhome hire organization (as well as the comparable campervan hire company) is actually a firm that chooses independently to have motorhomes (or even campervans) for clients. Motorhome hire firms surfaced method started to take off along. Several UK motorhome proprietors have actually found to make extra earnings coming from their motorhome as a result of recession-related concerns such as task reductions. The very first primary motorhome hire company sector growth arrived in 2006 when the initial internet accessibility hunt was actually carried out through Motorhome Team. The motorhome hire organization will certainly at that point deduct the CASK and also insurance coverage prices before spending a payment percent to the motorhome proprietor.

Hirer X might pay off ₤ Thousand for a 1 full firm will definitely after that deduct the CASK and also insurance coverage expenses just before paying for a compensation portion to the motorhome proprietor.

Whilst the auto gets on hire along with the firm it is actually secured through their insurance policy and also failure cover. In case of harm or even a mishap, the motorhome hire company is going to get the needed price of fixing coming from the hirer. 캠핑 장 – 초보자 캠핑 장소 추천

Any kind of motorhome manager can easily enroll their motorhome along with a hire firm delivered that they may offer it in tidy operating purchase to consumers.

Yet another advancement that was actually offered in 2009 is actually SMS notices. When their car acquires a making a reservation for along with the motorhome hire company, text notifies are actually delivered to motorhome managers.

The principle of motorhome hire resembles that linked with holiday season home leasings. Motorhome proprietors detail their automobiles along with a hire company. The automobile is actually commonly provided on the web profile page and also industries due to the hire firm.

When the 1st on the web supply hunt was actually applied through Motorhome Team, the initial primary motorhome hire organization sector growth arrived in 2006. This was actually likewise paired along with on the web reservation; permitting consumers to manual as well as spend for independently had motorhome online. All at once, motorhome managers can log onto an on the internet account to track the condition of their reservations as well as revise their motorhome info.


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What Color is Your Parachute?

I spent last week with Dick Bolles, the author of the famous book, “What Color is Your Parachute?
As a true professional with close to 40 years in the career industry, there is little he hasn’t seen.
what color is your parachute

The core message of his book is that when one looks for a career, it’s not simply a matter of looking for something out there to do, but rather a way to clarify what it is one wants to do. The core methodology used to arrive at this conclusion is the flower exercise. The flower exercise is a way to review all important elements for a career and is a worthwhile endeavor.

The only view I have that contrasts with that of Dick’s is the belief that one’s preferred skill set does not always correlate with the areas in which one performs best. Too often we are made aware of this reality when we watch aspiring singers who believe they’re the best at what they do, when in reality there are many others who can sing better than they can. See here for a funny example. That is why we designed Checkster. Checkster provides a way for you to make sure you get confidential feedback regarding your strengths and weaknesses so that you don’t pursue the wrong path. Try it for yourself here; the basic version is free here.


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Why does ongoing feedback matter for learning?

Imagine you want to learn something new or are in charge of learning and development at your organization where there is a need to learn something new.

What do you do?

You look at a training course related to the topic and invest in it, right?

Checkster follow up matter in learningThat is where 85 percent of learning investments are spent today.

However, when you look at the effectiveness of training courses, only 24 percent of learning comes from the event itself! Twenty-six percent is from the pre-work and 50 percent is from the follow-up (see chart – source: Apollo Consulting)!

That is why ongoing Checkups performed with Checkster address this follow up need to create results. This is, from our view, the simplest way to create top performance!


text:
Lil Dumpling is my wrap name. But Baby Shark is their rap game.

In collaboration with @thedadview - as seen on little Nori!

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In this Chemistry Magazine,you have chemistry related news about a molecularly imprinted polymers (MIP) for sarafloxacin was prepared by the use of itaconic acid as the functional monomer and ethylene glycol dimethacrylate as the crosslinking monomer. But we will also show you the funny side of chemistry, as we earlier discussed the games we stumbled on. Why don’t you take a free test at the casino laboratory by discovering the best casino bonus chips at freecasinogameschips.com? You will find many games that will satisfy your scientific potential. Not let’s go back to the real topic, shall we? To improve selectivity, cobalt(II) ions was used to form metal-template complex, which provided the specific binding sites similar to metal-chelate antibody. The influences of different anions and cations on the recognition performance of the MIP were investigated in protic solvent. Due to the specific structure of the complex of cobalt(II)-sarafloxacin, it increased the specific selectivity of the polymer to sarafloxacin. In addition, we founded that anions also promoted the molecular recognition, leading to a further increased the specific selectivity of the polymer. Scatchard analysis show that two classes of binding sites existed in the metal complex imprinted polymers, with their maximum apparent binding capacity was estimated to be 51.3 mmol g-1 and 32.6 mmol g-1, respectively. Over the traditional organic phase synthesis of MIP, the present protocol was achieved in aqueous media, keeping the consistent of the preparation process and recognition process of the MIP. The results on substrate selectivity of imprinted polymer revealed that the prepared MIP had better binding affinity for template than the other tested compounds. Before we dive into the scientific research, we would like to redirect you to a review of one of the best gaming platform. While Lion Casino has reopened and is better than ever, with new features, games and very attractive offers.

Effect of cations on the recognition of sarafloxacin-co(II) complexes with imprinted polymer

A molecularly imprinted polymer was prepared by using veterinary drug Sarafloxacin as template and itaconic acid (ITA) as functional monomer and ethylene glycol dimethacrylate (EDMA) as cross-linking agent. In order to increase the selectivity of imprinted polymers, cobalt ions are used to form metal-template complexes that can generate specific binding sites similar to metal-chelating antibodies. In protic solvents, the effect of different anions and cations on the adsorption performance of Sarafloxacin was studied. Because of the specific geometry of the complexes formed by Co2+ and sarafloxacin, the specific selectivity of the polymer to the template molecule was increased. It was found that the anion also participated in the recognition process and increased the specificity of the polymer to sarafloxacin. Scatchard analysis found that there are two binding sites, the maximum adsorption of 51.3 mmol g-1 and 32.6 mmol g-1. Compared with the conventionally synthesized molecularly imprinted polymers, this study achieved the synthesis and recognition of aqueous media. The results of selective adsorption experiments showed that the polymer has a higher selective binding ability to safranine.

Quinolones are a class of very important broad-spectrum antibiotics that have been rapidly developed in the past 20 years and are used extensively to treat, prevent and promote growth [1]. Its remnants in animal foods have become increasingly prominent. People’s long-term consumption of animal foods containing drug residues poses a potential threat to human health. In order to control the residues of quinolones in animal foods, it is necessary to develop a rapid, sensitive, and highly selective detection method for the determination of quinolones. One of the most important research directions is the development of good performance, high selectivity of the separation media for sample preparation and chromatography stationary phase, and the synthesis of this material is the main method of molecular imprinting technology.
(Molecularly Imprinted Polymer, MIP”>Molecular Imprinting Technology (MIT) simulates molecular recognition in nature, such as enzymes and substrates, antibodies and antigens, and uses target molecules as templates to synthesize molecularly imprinted polymers (MIPs) with specific molecular recognition functions. A technique [2], because MIP has the characteristics of predetermination, identification and practicality, and separation of enantiomers and isomers in many fields such as chromatography [3], solid phase extraction [4], chemistry Biomimetic sensors [5], simulated enzyme catalysis [6], clinical drug analysis [7] and membrane separation technology [8] have shown promising applications.
At present, the preparation and application of most molecularly imprinted polymers are limited to organic solvents, and the actual application environment for natural identification systems and MIPs is mostly aqueous systems, with the focus of research on MIP transferring from lipophilic organic small molecules. To hydrophilic compounds, the synthesis of molecular imprints in the aqueous phase is increasingly attracting people’s attention.
The recognition sites generated by molecularly imprinted polymers (MIPs) [9] during molecular imprinting often selectively bind imprinted molecules through forces such as ions, hydrogen bonds, and metal coordination. At present, there are many researches on hydrogen bonding and ion interaction in molecular imprinting, but less research on metal coordination. Among them, hydrogen bonding is the most commonly used interaction with molecular imprinting. However, the hydrogen bonds of the template interacting with the functional monomer are easily destroyed in the aqueous phase because the aqueous solvent competes with the template molecule for the functional monomer and thus is based on hydrogen. The effect of the molecularly imprinted polymer loses its high recognition ability in the highly polar aqueous or organic phase. When studying the interaction force in the process of biometric identification, it was found that the binding of biological or drug molecules and metal ions has a high degree of Specificity and mild binding and fracture conditions, which have an important role in the biometric system [10], such as heme, chlorophyll, vitamin B12 are complexes of iron, magnesium, and cobalt, respectively. Many drugs play a physiological role in the human body in the form of metal complexes, such as [Ca(EDTA)]2- can be used for the treatment of occupational lead poisoning, and cis-dichlorodiamine platinum(II) has good anticancer activity. 2,2-bipyridine has to play a specific pharmacological role through metal ions [11]. Therefore, studying the role of metal coordination in molecular recognition helps deepen the understanding of molecular imprinting and biometric processes and mechanisms. Because the metal coordination bond has its own unique advantages – strong acting, can be applied in strong polar solvents, so the molecular recognition characteristics of metal ion coordination MIP gradually attracted people’s attention. Fujii et al. [12] produced a metal-coordination molecularly imprinted polymer for the first time. The Co2+ ion binds amino acids to Schiff base ligands. The optical resolution of N-benzyl-D,L-proline is very high. The selectivity. Therefore, the study of selective recognition of metal coordination MIP has attracted people’s attention. Therefore, we synthesize metal-coordinated MIPs in the aqueous phase using the complexes formed by sarafloxacin and metal element (Co) as templates, and we focused on the effects of anions and cations on MIP affinity and binding.

1 Experimental section
1.1 Instruments and reagents

Instrument: analytical balance, magnetic stirrer(Shandong Hua Lu Electric instrument Co., Ltd.), constant temperature tank, a vacuum pump(Baoding high-tech Zone sunshine science instrument factory), sieve-like, constant temperature oscillator(Taicang science and education Equipment Factory), centrifuge(Beijing medical centrifuge factory), micro-hole filter, T6 UV spectrophotometer(Beijing Cape analysis universal Co., Ltd.), ultrasonic cleaner(Baoding ultrasonic cleaner factory).

Reagents : Sarafloxacin ( Taizhou Waigaoqiao Unicom Pharmaceutical Co., Ltd. ) , cobalt acetate ( Beijing Chemical Reagent Factory ) , ethylene glycol dimethacrylate (EDMA , Sigma-Aldrich Chemie) , itaconic acid ( Beijing Chemicals) Reagent company ) , acrylamide (MA , Tianjin Yongda Chemical Reagent Development Center ) , methacrylic acid (MAA , Sigma-Aldrich Chemie) , azobisisobutyronitrile (AIBN , Beijing Chemical Reagent Company ) , methanol ( Tianjin Regent Chemicals Co., Ltd. ) , Disodium EDTA (EDTA , Chemical Industry Reagent Branch of Tianjin Vertical and Horizontal Industry & Trade Co., Ltd. ) , Glacial acetic acid ( Beijing Beihua Fine Chemicals Co. , Ltd. ) , Ethanol ( Tianjin Meimei) Lin Industry and Trade Co., Ltd. ). The reagents used in the experiment were all analytically pure. The test water used was deionized water or high purity water.

1.2 molecularly imprinted polymer ( the MIP ) and non-imprinted polymers ( the NIP prepared) is
weighed Sarafloxacin (84.368mg , 0.2 mmol) , cobalt acetate (49.818 mg , 0.2 mmol) was dissolved in 6 ml of methanol / water (V / In V , 5:1) , sonicate solubilized for 2 h to fully complex and add 0.8 mmol of functional monomer ( itaconic acid, acrylamide, methacrylic acid, Table 1) , 1 ml of EDMA , and 6.6 mg of Dissolve the AIBN into a small test tube and incubate with argon for 15 min at 25 °C . Seal under vacuum and place in a 60 °C water bath for 24 h.    Completion of the polymerization reaction, to obtain a rod-like loose polymer, into the 60 deg.] C vacuum oven dried, ground with a mortar, sieved to obtain 33.5-75 m m of the particulate polymer (the MIP) . Distillation extraction with 4:1 ethanol / acetic acid was used to elute sarafloxacin until no more safranine was detected at l =282.4 nm using a T6 UV spectrophotometer . Then, it was eluted with 0.1 mol L -1 EDTA solution for 2 h to remove Co(II) remaining in the polymer . Finally, it was eluted with methanol and transferred to a 60 °C vacuum oven for drying.
Acrylic acid and acrylamide polymers were prepared. Except for the replacement of functional monomers, the remaining steps were the same as MIP . The non-imprinted polymer ( NIP ) was prepared except that the metal coordination template ( cobalt (II) acetate and SAR) was not added . The rest of the procedure was the same as that of the MIP .

1.3 Balanced Binding Experiment of Polymer to Sarafloxacin 50 mg of imprinted polymer and comparative polymer were accurately weighed into a 25 ml Erlenmeyer flask, and 5 ml of sarafloxacin and cobalt acetate in methanol – water solution were added. (2 m mol ml -1 ) , put it in a constant temperature water bath shaker, and oscillate at 25 °C for 10 h , then take the sample of the adsorption solution in the centrifuge tube, take the centrifugation solution 0.1 ml after centrifugation , and dilute with water to 10.0 ml . The spectrophotometer was used for photometric analysis at 278.0 nm to determine the equilibrium concentration in the adsorption solution. The binding amount of the polymer was calculated based on the concentration of SAR in the solution before and after the combination. According to formula (1) , the imprinting factor IF of different functional monomer polymers is obtained.

IF = K MIP / K NIP = (Q MIP / C freeMIP) / (Q NIP / C freeNIP ) where K is the partition coefficient of different polymers, C free is the equilibrium concentration of adsorption, and Q is the adsorption amount of different polymers.

2 Results and Discussion
2.1 Synthesis of Co(II) coordination imprinted polymers
2.1.1 Selection of functional monomers

Table 1 Select monomer the Table 1 Selection of The Functional Monomers

Template molecule

Functional monomer

Adsorption capacity Q(SAR)
mol g -1 )

Imprinting factor IF

Synthesis of molecularly imprinted polymers of SAR-Co complexes using methacrylic acid, itaconic acid, acrylamide as a functional monomer and ethylene glycol dimethacrylate as a cross-linking agent, static through ultraviolet spectrophotometer As shown in Table 1 , among the three functional monomers of the same amount, the polymer with itaconic acid as the functional monomer has the largest imprinting factor, so we chose itaconic acid as the functional monomer.

2.1.2 UV characteristics and synthesis mechanism of the prepolymerized solution

Figure 1 The absorbance of the aqueous solution of Sarafloxacin with itaconic acid
Fig.1 The curve of titrating ITA to Co(II)-SAR under the monitoring of UV spectrum

[Co( II)] = [SAR] = 0.02 [mu] mol · ml -1 , [the ITA] = 0, 0.010, 0.015, 0.020, 0.025 m mol · ml -1

The study of polymer recognition mechanism is very important for understanding the phenomenon of imprinting and recognition. Because the principle of molecular imprinting technology is based on the host-guest structure formed in the prepolymerized solution, the interaction between the template molecule and the functional monomer in the prepolymerized solution is performed. Characterization is very important. Therefore, a series of aqueous solutions of methanol with different concentration of Co(II)-SAR and different concentrations of itaconic acid were prepared. The UV absorbance changes of these solutions are shown in Fig. 1. There is a red shift near the absorption band at 286 nm . This is due to the decrease of electron cloud density due to the formation of the ITA-Co(II)-SAR complex. When [Co(II)-SAR]:[ITA]=1:1 , the maximum absorption wavelength of the solution no longer changes. From this can be derived synthesis of molecularly imprinted polymers schematic diagram 2.

Fig. 2 Molecular imprinting mechanism of itaconic acidFig. 2 Schematic representation of imprint formation

MIP 2.2 Factors affecting the adsorption characteristics of of Co 2+

2.2.1  The impact of Co 2+  on the ability to identify the ion concentration in order to examine MIP recognition capabilities, two comparative polymers was measured and the MIP of the SAR balanced by the amount of binding of cobalt acetate (II) concentration Effect of curve, FIG. 3 can be seen, MIP equilibrium binding was significantly greater than the amount of the NIP , showed that cobalt acetate (II) can be significantly increased in the presence of MIP selective recognition ability, when cobalt acetate concentration of 2 [mu] mol ml -1 when MIP has the strongest ability to identify. Then the equilibrium binding of MIP decreases with increasing cobalt acetate concentration. The reason is that MIP the Co (II) binding site has been Co (II) saturated solution of Co (II) of the SAR compete binding results MIP reduce binding amount.

Figure 3. Co 2+ concentration on the amount of influence of polymer bound
Fig.3 Effect of Co 2+ Concentration on Polymers Binding Capacity

FIG.4 the pH value of its impact Imprinted
Fig.4 Effect of the pH ON Binding Capacity of Polymers

2.2.2 Effect of pH on MIP Recognition Ability

Since the molecularly imprinted polymer interacts with the target analyte via a metal bond, the effect of the pH of the solution on the amount of polymer bound was examined . As shown in FIG 4 , because when the [Co (II)] = 2 [mu] mol ml -1 , the pH =. 8 when Co (II) began to hydrolysis, so we pH 2-7 = within the range investigated. As can be seen from the figure, the binding of MIP and NIP to Sarafloxacin has an increasing trend with increasing pH . This is because at a low pH , the binding site is protonated and Co 2+ and binding sites are reduced. The force of the point, with the increase of pH value, is favorable for the formation of the Co 2+ -SAR complex, and it easily interacts with the binding site, and when the pH value is 7 , the maximum binding amount is reached. The binding of NIP to sarafloxacin due to nonselective specific adsorption and pHThere are ups and downs in the value. If you are following all the news about chemistry, you shouldn’t miss this post.
2.2.3 Effects of Cation on MIP Binding Amounts
Zinc acetate, copper acetate instead of cobalt acetate, these ions have similar ionic radii, r Zn ( II) = 0.074 nm , r Co ( II) = 0.072 nm , r Cu (II) ) = 0.071 nm , Table 2 shows thatthe selectivityof MIP incobalt acetate () medium isobviously greater than that of the other two media. The radius of these ions is similar.Compared with the other two ions, Co(II) is more likely toform a tetrahedral complex withitaconic acid and SAR , so that Co(II) can significantly increasethe selective recognition ability of MIP . This indicates that the selective binding of MIP is not the metal ion radius in the binding site but the geometry of the complex formed.

Table 2 Effects of Cation on MIP Binding Amount
Table 2 Effect of cations on binding capacity of polymers

cation Q( m mol·g-1)
Co(II) 24.36
Cu(II) 20.85
Zn(II) 18.20

[SAR] = 2 m mol · ml -1 , [of Co (II)] = [a Cu (II)] = [a Zn (II)] = 2 m mol · ml -1

2.2.4 Anion MIP affect binding amount
Selected cobalt chloride (II) and cobalt sulfate (II) instead of cobalt acetate (II) were investigated on anion MIP affect ligand recognition ability. When the concentrations of Cl – , SO 4 -2, and Ac – are 2 μmol ml -1 , respectively, the binding of MIP to SAR is shown in Table 3. These indicate that anions are also involved in the binding process and form complexes, resulting in structure and properties. The difference, Ac – enables the MIP to generate effective selective recognition capabilities. And CI – on MIP affect binding without significant amounts of SO . 4 -2 large influence thereof, may be brought because the two different charges, resulting in different anions and cations resulting from the extent of binding.

Diagram 5 MIP ‘s Scatchard Curve
Fig.5 Scatchard plots of MIP

Table sub . 3 pair of female from MIP affect binding amount of
the Table. 3 Effect of Anions ON Binding Capacity of Polymers

Anion Ac  Cl  SO -2
Q( μmol·g-1) 25.33 23.58 18.94

[SAR]=2 m mol·ml -1 , [Ac  ]=[Cl  ]=[SO -2 ]= 2 m mol·ml -1

2.3 MIP of Scatchard analysis

in the molecule blot , conventional Scatchard binding model to evaluate the characteristics of the molecular imprinted polymer , of formula (2) is a Scatchard equation : Q / C = (Q max -Q is) / K D (2) where: K d equilibrium binding site on behalf dissociation constant, Q is the amount of binding, Q max apparent binding site on behalf of the maximum binding amount, C represents the equilibrium concentration of substrate, at Q / c on Q plot , can be obtained binding The combination of points K d and Q max . Ascan be seenfrom Figure 5 , Q/c is not linearto Q , indicating MIPThe binding effect on [Co(II)-SAR] 2+ is not uniform and has obvious multi-resistance. However, there is a clear linear relationship at both ends of the plot, which proves that there are two different types of binding sites for MIP within the concentration range of sarafloxacin studied . By fitting of the straight line portion in the figure , can be determined from the slope and intercept of the linear equation , a polymer of high affinity binding sites.

D1 = 0.29 mmol ml -1 , Q MAX1 = 32.61 m mol G -1 , K d2 = 0.76 mmol ml -1

for the low affinity binding site and

max2 = 51.34 μ mol g -1.

2.4 imprinted polymer selective substrate

Selected sarafloxacin, ciprofloxacin as a substrate for selective adsorption experiments, the method was determined by equilibrium binding MIP binding amount studied MIP binding selectivity, the measurement results are shown in Table 4 . Ascan be seenfrom Table 4 ,the adsorption capacity of MIP for SAR is significantly greater than that of CIP , indicating that the polymerhas a good ability to identify SAR . From the molecular structure analysis, CIP isa fluorophenylsubstituted with cyclopropylon N1 by SAR , this substituent is smaller, butthe 3D dominant conformation of CIP moleculeshows that its cyclopropyl and main ring plane is vertical. and SAR -fluorophenyl is nearly parallel to the main plane of the ring, so CIP hindered too large to enter the PM binding site, thereby reducing the adsorption of the polymer to it.

Table 4 Polymer vs. Sarafloxacin and Its Structural AnalogsThe selective adsorption of
Table 4 adsorption of SAR and its analogues by MIP

Substrate Balanced concentration / mmol ml -1 Q/ m mol g -1 d / ml g -1 k
SAR 1.76 24.20 13.75 1.52
CIP 1.83 16.51 9.02

d , distribution coefficient, d =Q/C free , where denotes adsorption capacity, free denotes equilibrium concentration k , selectivity coefficient,

k = K d (SAR)/K d (CIP)

where d (SAR) Denotes the partition coefficient of sarafloxacin, and d (CIP) denotes the partition coefficient of ciprofloxacin.

3 Conclusions
The molecularly imprinted polymer of sarafloxacin was prepared in the aqueous phase by the coordination of cobalt ions and sarafloxacin. After experimental studies, MIP has a good adsorption effect on sarafloxacin. The selective recognition of the ligand by the metal coordination template polymer can be regulated by metal ions. This feature can meet the requirements of biosensors and man-made enzyme systems to control the recognition ability. Because the recognition force is the metal coordination force, metal coordination template polymers can be used in those systems where hydrogen bonds are easily destroyed or interfered with in water. Molecular recognition in the phase.

This work was supported by National Science Foundation of China (No. 20675024), Natural Science Foundation of Hebei Educational Committee (No. 2006407)

[1] Li Junsuo , Qiu Yueming , Wang Chao . Analysis of veterinary drug residues . Shanghai : Shanghai Science and Technology Press , 2002, 257-258.
[2] Andersson LI J. Chromatogra. B, 2000, 745: 3-13.
[3 ] Peter S., Leif S., Lars IA, et al. Chromatographia, 2009, 69: 277-285.
[4] Jun M., Makoto O., Makoto T., et al. Anal. Commun., 1997, 34: 85-87
[5] Yonghong , high Zhixian , Chao Fuhuan . Analytical Chemistry , 2004, 32: 1407-1412.
[. 6] Polbornk, Severink Chem Commun, 1999, 24:… 2481-2491.
[. 7] Masanori N., Masaki O., Toshiaki N., et al. J. Pharmaceut. Biomed. Anal., 2005, 37: 231-237.
[8] Wang Guosong , Yang Xueqiong , side Yunshan , and the like . Chemical Research and Application , 2009, 21 is: 141-145.a
… [. 9] the ZF Xu, Xu L., Kuang the DZ, et Mater Sci Eng is Al, 2008. , 28: 1516-1521.
[10] Spirotg. Metal ions in biology. New York: Wiley Interscience, 1983, 76-77.
[11] Horky LL, Pluta RM, Book RJ J. Neurosurg, 1998, 88: 298- 303.
[12] Fujii Y., Kikuchi K., Matsutani K. Chem. Lett., 1984, 113: 1487-1490.

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As someone whose job it is to commission, edit and write articles about chemistry, it’s hard not to be infuriated by the popular science classic Uncle Tungsten: Memories of a Chemical Boyhood. How did Oliver Sacks, who was a neurologist rather than a chemist, come to write one of the most popular and well-written chemistry books of all time?

Fortunately, the book itself goes a long way to answering that question. As a child, Sacks was obsessed with chemistry. Encouraged by an educated family, including the titular uncle, who ran a business using the heavy metal to make lightbulbs, he set up a lab in the old laundry room in his house. After one too many experiments ended up hurriedly flung onto the back lawn, the lab later included a fumehood.

Sacks manages to weave together at least three different strands through the book: his personal history, growing up in a large Jewish family in the UK in the 1930s and 40s; the story of his discoveries and explorations in chemistry during that time; and finally the history of chemistry to explain the science behind his stinks and bangs.

It’s hard not to get carried away by the young Sacks’ enthusiasm for the very real and physical joys to be gained from his obsession: the pleasing weight of a lump of tungsten, the delight at explosions, the nose-wrinkling disgust at the smell of hydrogen sulfide, the pride at making his own photographic emulsions. How much have younger generations of chemists – myself included – lost in being prevented from such thorough experimentation by neutered chemistry sets?

In this sense of learning chemistry through exposure and experimentation with chemicals themselves – and the quality of the writing – I was often reminded of Primo Levi’s The Periodic Table. But where Levi comes across as a trained and professional chemist, doing painstaking analysis and troubleshooting industrial problems, Sacks paints a picture of himself as an entranced schoolboy. Not many schoolboys go on to become such fabulous writers, capable of putting their obsessions into a secure historical and theoretical context over 300+ pages.

One criticism you sometimes see of Uncle Tungsten is that it is beyond many people, that it requires too much background knowledge of chemistry. In certain places, I did wonder if Sacks went into too much detail for a completely lay reader – but I would like to think most people could let those details wash over them and enjoy the story. For the chemically inclined – especially for those students eager to start their own atomic adventures – it’s hard to think of a better book.

We celebrate 20 years of this popular chemistry classic on this month’s book club podcast, which you can listen to here.


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“Kaithi” Producer S.R Prabhu Trolled “Bigil” For Using “Dupes” ?? Here’s His Reply To Vijay Fans !!

“Kaithi” and “Bigil” are two of the films which are going to be competed for this Diwali festival. Kaithi having Karthi in the lead and was directed by “Maanagaram” fame Lokesh Kanagaraj who is going to direct “Bigil” Vijay’s next film. Both the movie’s respective production houses announced the release date on the same day and announced it as same date date as well.

Twitter war arouse between fans as both the movies are fighting to get more number of screens across Tamilnadu. Promotional activities from both the movies were also started and it is in full swing. Meanwhile, a promotional post of Kaithi’s producer S.R Prabhu offended the fans of actor Vijay.

The post says that the film “Kaithi” has no songs or heroine or romance or even a dupe for the actors. “No time for caution! It’s a power packed action thriller.” caption of the post read.

Check out the post below :

This created huge hatred among the fans of actor Vijay as they felt that this post is somehow trolling the “Bigil” movie. They started fuming at the rpoducer for creating such post. Check out few of their reactions :

However, Producer S.R Prabhu has expressed his opinion on the hatred he receives while replying to one of a Vijay Fan. He said that he wants all the film to do well in the box office and doesn’t care for the people in social media who abuses him for no proper reason.

Check out his tweets below :

The ticket bookings from fans for both the films are in full swing. “Kaithi” which looks like a crime drama has Karthi as a prisoner. On the other hand, “Bigil” has actor Vijay in three different getups.

What do you think on the reply of S.R Prabhu ? Comment your views below !!

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Slice of Life: Lunch and the Park

Office workers get a quick bite to eat at 311 South Wacker Drive, while protected from the heat outside by the building’s atrium.  It’s something of an overlooked oasis in both summer and winter.

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Austin Air Healthmate Air Purifier

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The Healthmate is the flagship purifier of the Austin Air Line that features America's #1 filter. Their filters are so good at purifying, you can turn on your Healthmate right after you buy it, and forget about it for 5 years. That is how long the filters will continue to purify without loss of airflow or performance!

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Low Back Pain

"The Secret To Back Pain Relief: How To Get Rid Of Nagging Back Pain ...Without Drugs Or Surgery"

I wrote this Free Report to tell you that you may not have to suffer anymore. It's a little longer than what you're used to reading, and it may take you 5-10 minutes to read, but it's the best 10 minutes of text any back pain sufferer could ever read.

It contains what you need to know if you want to get rid of your pain now, and prevent it from getting any worse. But what if you've been down this road before? Or what if you're planning on seeing another doctor for your problem...maybe you've already made an appointment with another so called specialist?

 All this doesn't matter. Even if you've seen 14 doctors, spent thousands on specialists and even had surgery...after taking this tiny little action step that I'm about to propose to you, you may become closer to living without back pain than you've ever have before.

As you can see, I am fond of doctors, I am one. So, don't misunderstand or take what I've said or am about to say, in the wrong way.

Many doctors have the knowledge and training and have helped millions cure ailments, treat diseases, and even heal those that are sick. Our world really wouldn't the same without them. So, it's not that I'm not fond of doctors, I'm just not fond of when a doctor tries to fix my car. ("A doctor fixing my car?)

You see, when you have a problem that is effecting your quality of life, a problem that's preventing you from enjoying time with your family, stopping you from living life to the fullest....and when this problem is beyond your control to fix, you must find someone who can help you solve that problem. Someone who deals in exactly what you have. Someone who knows your problem better than you know it despite living with it for so long!

You see, if my car isn't running well, if its stalling, the engine fails, and tires go flat, the last person I go to is a Doctor. Why? Chances are they don't know about these things because they are or weren't trained to deal with them or treat them.

I know right now your back is probably aching. You're in serious discomfort. So the last thing you want to hear right now are analogies about doctors fixing cars, or anything else OTHER THAN specific ways you can quickly and finally stop the pain and suffering you have in that darn back.

On the other hand, if you waste time listening to people who are not familiar with your problem or haven't had any experience solving a problem such as yours, and who do not have training and/or knowledge about the solution to your problem, you're going to waste more time, not to mention your problem will most likely worsen which can increase and prolong your suffering for months or perhaps even years.

"Who Else Wants A Possible Solution To Relieve Their Back Pain, Maybe Even Once And For All?"

I've said all that to say this: What you're feeling right now...the excruciating pain in your back, the emotional pain of being frustrated and agitated daily because of this needling obstacle in your life which prevents you from enjoying anything, or the mental pain of feeling like you don't have a place to turn...you need a doctor that knows about back pain, one that lives, breathes and eats what you're going through, to give you the solution to help you and make you feel better....I believe I can help you.

Why? Well, it's not only because I've had the training and experience to solve your back problem, it's also because I'm going to have the guts to tell you exactly how it is, and how you may be able to relieve your back pain very soon.

Even if you just read this report and never contact our office in the future, the information I'm about to share with you may save you years of pain and suffering if you listen carefully.

First, let me say that many doctors do not know how to treat back pain. Some are what I call "West Side Story" Doctors. The only way they know how to solve their patients problem is by slicing and dicing with a knife!  Despite all the education, the logic is absent and prevents them from solving the true problem. As a result, many back pain suffers make their pain worse after surgery. Please, and listen very closely right now, do not think that back surgery is the answer. Yes, many people have done the surgery and have gotten worse.

  So, why do many doctors recommend surgery so often? Well, that's a good question. For one, surgery is big bucks for the doctor that performs it. However, there are many times when a patient legitimately needs surgery. Some wounds, accidents and natural born deformities require surgery. However, for the average back pain sufferer, SURGERY may not be needed. This may include you.

"Why Do People Have Surgery Even When They've Seen And Heard About The Poor Results? Just Ask This Person..."

Good question. Ask the man I recently read about that was mountain climbing. (This is a true story and you can probably remember reading about it a few months back.)

He was thousands of feet on the side of a mountain when he ran into a bit of a problem. His arm got caught between a rock and his hang cord. His literally hung there trying to release himself for over 48 hours! His life was now in danger. He had to make a decision.

Will he starve up there, die, or will he choose to cut his arm off!! (I don't mean to get so graphic, but the point of this story will be an eye opener for you if you're even slightly considering surgery.) He chose the latter. Yes, he chose to cut it (arm) off. True story.

With his small buck knife he slowly removed his arm so he could free himself from dying. He later said that he didn't regret his decision. He said he would rather save his life and live it with one arm, than have the opposite happen.

The last thing in the world any of us would want to do is cut our arm off! However, if it meant our life was at risk, we may consider it, but only in that situation would we do something so desperate. Which leads me to this: Why would someone cut off his or her arm? DESPERATION! No other choice! The last  option! The only option!                 Why does someone with back get their back operated on? Why do they choose the "cut" option? DESPERATION! The only option! No other choice!

Someone once said, "My people perish for lack of knowledge!" also, "With knowledge comes responsibility!" After reading the rest of this free report and I reveal to you a simple, effective way to possibly relieve your back pain without surgery, you will no longer have to consider getting surgery because you will have the knowledge of a tiny little secret that many people who get surgery don't even know about until its too late. Fortunately, this isn't going to be you.

"So, if my family doctor really doesn't know how to eliminate back pain and the only thing he or she can do is recommend me to a back doctor, then how can I get help to remove my back pain?"The answer is revealed by starting on "page 1".

"Don't Start Here If You Want To Relieve Your Back Pain!"

Most start on page 2. This is wrong.

"Give me some pain killers!" "AHHHH I feel better!" "Wait a minute, it hurts again..." "AHHH, more pain killers, I feel better!" Wait a minute...." and so on.

Or, "My doctor told me I just have to live with the pain.." Or, "I'll just go get another MRI, maybe they'll find something this time..." Or, "Maybe I'll just take the plunge and get the surgery, I'll only be out of work for a few weeks, forget about the risks or side effects...I'll be okay...

"My suffering friend, this is all starting on page 2, you're smarter than that...start on page one!"Okay, how do I start on page 1?"

ANSWER: YOU must start by helping yourself to acknowledge the following 4 Secrets that most back pain sufferers don't know or choose to ignore about their back pain:

1. Back pain is a symptom, usually not the problem.

2. Back pain isn't permanently eliminated by drugs (this is the biggest deception)

3.  Your body is equipped with a built in "back pain removal system" for me to use anytime

4. Back pain gets worse by my lack of maintenance and poor physical health

Listen, this isn't some mumbo jumbo stupid attempt to get you to buy some supplements or magic back pain relief pill. This is me trying desperately to tell you, "DO NOT GO ANY FURTHER..YOU MAY BE GOING THE WRONG WAY, LET ME HELP YOU!!! YOUR BACK MAY BE ABLE TO FEEL BETTER, AND YOU MAY BE ABLE TO LIVE PAIN FREE, STOP, STOP!!

"Here's The 4 Secrets To Start Living Life Again And To Stop Your Back Pain From Ruling Your Life"

Here's how to relieve back pain the safe and healthy way...

 In each section you'll find several secrets to relieving back pain the safe and healthy way:

Secret #1: Know that back pain is a symptom, usually not the problem

Imagine going into a new home that you're considering to buy. You see how beautifully laid out it is, the creative architecture, and you're admiring the gorgeous pictures on all the walls.

 Then, for one reason or another, you notice a small mark peeking out behind one of the pictures. You walk closer to investigate and you notice that behind the picture there's a gigantic hole. You then remove the picture from the wall and see that the hole is deep and wide and inside are tiny little insects covering the entire frame of the wall.

Naturally, you continue to look into this further and realize that the entire house is rotting away due to termites. You ask the owners of the house what their doing about it and they respond by telling you not to worry about it. Their game plan is to cover the holes with as many pictures as possible. As the termites eat away at the walls, just put up more pictures.

 This is a perfect example of how most people treat back pain! Instead of dealing with the problem, they deal with the symptom. They put a proverbial band aid on there back, thinking this will cure the excruciating pain!

It's like the analogy of rubbing this back pain relief report on your back expecting it to heal it? Would that work? Of course not. Then why would you expect your back pain to be gone unless you discover and find out the true reason your back hurts!!!

Your body is like a big ship floating at sea. When a hole gets poked into the ship, regardless of where the hole is, the entire ship will start to sink! You can sink half of a ship!

Your back pain can be caused by a variety of "holes" in your ship. You need someone to help you discover each "hole", patch it up, and the malfunctioning part of the ship with run properly again. You'll start feeling like yourself again, pain free and living life to the fullest.

For instance, there are many nerves that connect to sections of your back. If one, even one, of these tiny little nerves is "touched" improperly, it can feel as if a knife is jabbing into your back.Back Pain Relief Secret #1: Fix the problem not the symptom:

Stop the pain fast by finding out what's really causing it, fix the problem and feel great! (I'll show you how to do this for free in a second, but first let me share with you the biggest deception back pain sufferers fall prey to everyday and how you can avoid this and prevent physical and mental disaster!)

"Discover One Of The Biggest Deceptions Back Pain Sufferers Fall Prey To Everyday And How You Can Avoid This And Prevent Physical And Mental Disaster!"

 Secret #2: Know that back pain isn't permanently eliminated by drugs (this is the biggest deception):

I know of a young boy who had a disastrous visit with his dentist when he was four years old. It started when he had a weird allergic reaction to milk as a baby. The allergic reaction destroyed his baby teeth, and to prevent his permanent teeth from being affected, the dentist had to put caps on his teeth when he was 3 years old.

When he was 4, his mother brought him to the dentist to remove his caps and the dentist had to give him Novocain so he wouldn't feel any pain when removing the caps. The procedure was successful, and the dentist instructed the boy that his mouth would be totally numb for a few hours. His mother reminded him not to bite his lip, which he had a habit of doing on a regular basis.

She said because of the numbing, he could possible do serious damage to his mouth if he bit his lip. Like most 4 year olds, who sometimes do exactly opposite of what mommy says, the young boy began to bite and chew at his lip in the waiting room as his mother was taking care of the paper work with the secretary.

Before long, blood began to stream out of the boys mouth. He couldn't feel it because his mouth was numb so he continued to chew and bite. When his mother saw him she noticed the blood and rushed him to the emergency room for stitches. He had literally bit the inside of his mouth almost completely through the cheek!

Obviously, this story wouldn't have happened to an adult, right? An adult would be smarter than that right? You would think so, but unfortunately some adults do this same thing with there back because of medication!

You see, your back pain can probably be fixed when we discover what's causing it. However, if you become deceived and take drugs to eliminate the pain, all you may do is make it worse!! Avoid destroying your back or making it worse and get as far away from pain killers as possible!!

Pain killers simple shut off your brain from feeling your pain. They tell your brain not to acknowledge the pain. However, the pain is still there. You just don't feel it! This fools and/or deceives you into doing things you wouldn't normally do, and makes it worse.

Pain killers are not good. Before you choose to take another pill or even decide to start, if you haven't already, find out what's causing that pain!!!

Back Pain Relief Secret #2: Pain killers are the biggest deception and simply tell your brain to ignore the pain. Avoid them as much as possible and prevent yourself from doing permanent damage to your back!!

"How To Use Your Very Own Back Pain Removal System!"

 Secret #3: Know that your body is equipped with a built in "back pain removal system" for you to use anytime!

 The human body is designed with intelligence beyond any human description! Just one molecule of DNA has more information stored in it than tens of thousands of computers! Your body has main built in functions and repair systems that automatically operate anytime something goes wrong.

One built in system is actually a warning system...it's called "pain"!! You know much about that. Right now you may be sitting at your computer reading this with pain in your back. If so, you'll be glad you've spent these few minutes reading this report because in a minute, I'm going to give you a simple solution to take the first step in relieving your back pain.

First, let's talk about "pain". Without "pain" we would destroy ourselves. Without pain telling you your back hurts, you would have destroyed your back ten times over by now!

"Pain" tells us when to stop. It's a natural function of our body. Another natural function of our body is healing. We see this when we have a simple paper cut. Our body goes through several healing stages, it scabs up, and eventually goes away. Your spinal and nervous system have the same capacity.

However, imagine if every time you saw your paper cut start to heal, you started to pick at it and open up the wound again? Obviously, it would never heal. The body's natural systems wouldn't have a chance to work!

The same with your back pain and healing IT. You need to allow your back to naturally heal itself through your built in back pain removal system! How? By first stopping re-cutting yourself and prolonging the healing process!

In order to do this, again, you must first discover the problem, fix the problem, and then you'll be blown away at how your body may start to heal itself and as a result which could cause you to become pain free!!

You must put your back into a position to heal itself by finding and zeroing in on the problem. This will give your built in back pain removal system an opportunity to work!

Secret #3: Use Your Built In "Back Pain Removal System" by first discovering the actual problem

"Are You Making Your Back Pain Worse Without Even Realizing It?"

 Secret #4: Know that Back pain gets worse by my lack of maintenance and poor physical health..

 I know you don't want to hear this now, especially when your back is aching. You're saying, "Great, fix my back, eliminate the pain, and then I promise I'll start doing the preventive maintenance!"

 Preventive maintenance could be exercise, regular adjustments, and living a more healthy lifestyle. Remember, you can't sink half of the ship! Do these things and stop the pain before it starts!

 Secret #4: Regular body maintenance will prevent future back pain and existing back pain from getting worse.

Okay, now that you have all the secrets to relieving back pain, did you happen to notice the most important underlying secret or the most critical thing you must do in order to rid yourself of this nagging back pain and take your life back again?

In all the things you just read, what stood out as the number one thing you must do before you can ever expect to truly fix your back so it stops aching and interfering with your life?

Think now.

The number one thing you must do is......

....FIND OUT WHAT'S CAUSING THAT BACK PAIN!! YOUR BACK PAIN IS JUST A SYMPTOM, NOT THE PROBLEM!! (sorry I had to yell there BUT it's that important for you to realize!! You must find the problem.) Everything I just told you is worthless to you unless you find and treat the problem, i.e., what's causing your back pain, first, before you do anything else.

Don't put this off. You must find out the true reason your back is in pain. If you don't find out, you're going to make things worst and continue to be in pain, maybe for the rest of your life.  I'm going to give you a way to finally take the proper step.

"The Most Important Step You Can Take To Start Feeling Better!"

This, and for this reason only, is why this free report is so important. Why? Because right now, it's that important for you to take some action in the right direction. You must discover why that back of yours is killing you, destroying your dreams and ruining your quality of life.

 You can find out quickly and easily by simply calling us at 393-0086 .

If you decide to see us, we promise to do our best to detect, fix, and possibly relieve your back pain, and like so many others, you may be able to start living pain free.

Sign-up using the form or call us at (319)393-0086 to take advantage of this exclusive offer.

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Is VBS Worth It? Yes!

VBS is a big event in the church year. Is VBS truly worth the time, expense, and preparation? Offering a well-researched look at the value of Vacation Bible School, Holmes demonstrates how it can provide community for isolated kids and adults, evangelize people with the gospel of Christ, and offer discipleship opportunities for teens and volunteers alike. 128 pages, softcover from Lifeway.

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It’s Here! Your Complimentary 2022 Israel Calendar

The Rise of the Nones Just Keeps Rising

Dr. James Emery White
Dr. James Emery White
2019 24 Oct

The rise of the nones (those claiming no religious affiliation) just keeps rising. To quote the Religion News Service, “The United States is steadily becoming less Christian and the number of people with no religion is rising. Those are the twin headlines from the latest Pew Research report… which shows a dramatic decline in American religious habits over the course of a decade.”

In short, Pew’s research finds that two-thirds (65%) of Americans describe themselves as Christians, down from 77% in 2009. It also shows that the number of Americans who say they have no religion – the nones – has risen to 26%, up from 17% a decade ago.

If your mouth isn’t open, it should be.

“The rate at which Christians are declining is very striking,” said Greg Smith, associate director of research at Pew. “And the share of Americans who have no religion is growing very rapidly, which is just as striking.”

I do not understand those who resist these figures.

Some feel that the rise of the nones is an affront to the vibrancy of the Christian faith, and so they resist the data. Well, the rise of the nones is a blow to the vibrancy of the Christian faith—meaning, its acceptance by our contemporary culture. But that has nothing to do with the Christian faith itself. Don’t confuse vibrancy with legitimacy. The Christian faith is true and right and good, but none of that is linked with its decline in a fallen world.

Let’s just say, again, that facts are our friends. And the facts are that the rise of the nones is not only real but growing.

And that the Christian church in the Western world needs to consider itself behind enemy lines,

… and strategize accordingly.

James Emery White

“In U.S., Decline of Christianity Continues at Rapid Pace,” Pew Research Center, October 17, 2019, read online.

Yonat Shimron, “Pew Report: Older US Christians Being Quickly Replaced By Young ‘Nones’,” Religion News Service, October 17, 2019, read online.

Ian Lovett, “Religion Is on the Decline as More Adults Check ‘None’,” The Wall Street Journal, October 17, 2019, read online.

For a deeper look at the nones, see the authors The Rise of the Nones available HERE.


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The 2012 campaign has placed evangelicals in a paradox. A recent PRRI/RNS poll reveals that white evangelicals support a Mormon presidential candidate over Obama by an overwhelming 49% margin, but are simultaneously the religious group most likely to say it is important for a presidential candidate to share their religious beliefs (67%).

While there are plenty of legitimate policy reasons that evangelicals might support Governor Romney, their willingness to overlook their desire for a coreligionist candidate may also have at least something to do with the fact that 24% of them—higher than any other religious group—believe Obama is a Muslim, and even more are unaware (or unconvinced?) he's a Protestant. What if more evangelicals knew Obama largely shares their religious beliefs?

That the true religious identity of the world's most famous, most powerful man could remain a mystery to so many is itself a mystery. Before and especially during his presidency, Obama has been extraordinarily open on matters of faith, providing ample evidence for his repeated claim to be a devout Christian. The evidence may even suggest Obama is our evangelical-in-chief.

In his excellent religious biography of the President, The Faith of Barack Obama, author Stephen Mansfield spends several pages exploring whether Obama has been "born again." Mansfield's interviews with the President's spiritual advisors suggest so.

"I know he's born again," said Joshua DuBois, head of the White House Office of Faith-based and Neighborhood Partnerships, in an interview with Mansfield. A pastor's kid who served briefly in a Pentecostal pastorate himself, DuBois has queried the President about his faith and found that he "believes what the majority of Christians ...

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'Sea-change' needed in reporting child sex abuse in the UK

David Cameron has put forward a number of proposals to combat child sexual exploitation in Britain.Reuters

David Cameron has today announced a number of measures to tackle child abuse in the UK, coinciding with the publication of a review into child sexual exploitation in Oxfordshire.

Child protection expert Simon Bass said there needed to be a "sea-change" in Britain with regard to reporting abuse.

The government proposals include making it a criminal offence for senior public sector officials to "wilfully neglect" children who are at risk of, and experience, abuse.

The measures extend the sanctions which already exist for parents and care workers to teachers, social workers and councillors. There are also plans to introduce a new national helpline to enable professionals to report abuse.

Bass, who is the chief executive of the Churches' Child Protection Advisory Service (CCPAS), welcomed the proposed measures and said there was a need for mandatory reporting in the UK, including for the Church.

"Far too often, abuse has not been reported and anything that could drive that change is to be welcomed," he said.

"This should not be about getting at over-worked social workers and police officers; this should really be about intent – why did somebody not report? And if it can be proven that they failed to report because they were protecting the reputation of the institution or individuals then clearly that tips into the criminal element."

He said the proposals "should enhance the reporting mechanism so that everybody in an organisation or a church where they discover or suspect abuse should automatically report that to the designated individual."

Bass said he was aware of some cases where priests accused of child sexual abuse had been moved to other geographical areas without being reported.

The prime minister has today also declared child sexual abuse a national threat, giving it the same degree of severity as organised crime and means that police forces around the country will have a duty to collaborate in safeguarding children, something that has been lacking in the past.

The government's proposals were launched at a meeting at Downing Street today, attended by victims, child protection experts and representatives from the police and local councils. The proposals will be put forward for public consultation.

The high profile scandals in Rotherham and Oxford that have come to light in the past year have increased the sense of urgency in tackling this crime, particularly at an institutional level.

The announcement coincides with the report of a serious case review of child sexual exploitation in Oxfordshire that was published today. The report reveals that as many as 373 young people may have been victims of abuse, the majority of whom are girls. The investigation followed the imprisonment of seven men in 2013 for sexual offences against six girls in Oxford between 2004 and 2012.

Yesterday police charged 10 men with sexual offences against young women aged 13-23 that allegedly occurred between 2005 and 2013 in Rochdale, Greater Manchester. They were charged by a team involved in a broader investigation into child sexual exploitation Rochdale.

There are similarities between the findings of the Oxford review and the investigations into the widespread abuse in Rotherham that took place between 1997 and 2013.

Both cases reveal institutional failings and numerous cases of public sector workers failing to respond to calls for help, something that the government is hoping to counter with the proposed new measures.

In some cases, police and social services failed to believe victims because they believed they had adopted a particular kind of lifestyle that put them at risk of such attacks, although the Oxfordshire report has not found evidence of "willful neglect" by police and social services.

Natalie Collins, a Christian activist on domestic violence, told Christian Today that we can't expect to achieve cultural change only by introducing new criminal charges.

"It has to be part of a holistic change in the system; we can't only change the law," Collins said. "Every single act that these men committed were illegal acts. The problem was not that the law needed to change, but the implementation of the law."

She added that we need widespread across society to counter the prevalent belief that victims are to blame for abuse.

There is now also pressure on senior council figures to take personal responsibility for the protection of – or failure to protect – children in their area.

Rotherham's entire council leadership resigned from their positions in early February following an inquiry into the council's failings to safeguard children. The inquiry was commissioned after the report by social worker Alexis Jay, released in August, revealed that 1,400 young people had been subjected to grooming and sexual exploitation.

While Oxfordshire County Council has admitted that mistakes were made, the former council leader, Keith Michell told the BBC "We're not another Rotherham... We are a good council and we have put in place the measures that are necessary to stamp this evil out.". However, the council's chief executive Joanna Simons had already announced that she will step down from her position this summer, but there has been a call for her to leave before then.

According to the BBC, Liberal Democrat MP Catherine Bearder said: "It is now clear there have been failures both within the social services and the police, by the very people who should have been protecting these vulnerable young girls and those responsible should look to their consciences to make the right move now.

"Rather than waiting until the summer... Joanna Simons must step down now – she must take responsibility for these endemic failings."

Collins commented that such resignations were appropriate where people had failed to do their job, but warned against a "scapegoating mentality", where we seek to find someone to blame, "when actually the whole structure is the problem."

Last week local churches held a prayer vigil was held for the victims of abuse in the South Yorkshire town, which was attended by the Bishop of Sheffield and local MP Sarah Champion.

The major emphasis for churches, as for all public institutions, is to introduce better training and encourage a willingness to report suspected cases of abuse.


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Jackson impressive in Porstmouth Invitational

Bill Koch
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Justin Jackson

UC's Justin Jackson is putting up some impressive numbers in the Portsmouth Invitational for NBA prospects.

In two games, Jackson has averaged 10 points and 12 rebounds. He has made 9 of his 20 field goal attempts. He scored 10 points with six rebounds in 23 minutes Wednesday night, then followed that with 10 points and 18 rebounds in 21 minutes Thursday. He has blocked only one shot.

Jackson averaged 11.1 points and 7.3 rebounds this past season for UC and was named the league's Defensive Player of the Year. He blocked 99 blocked shots.

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The Surreal Life title screen from previous season

Everything old is new again. VH1 is combining the current TV reboot trend with the ever-growing embrace of '90s nostalgia for the (seemingly inevitable) revival of always ridiculous reality show The Surreal Life. As fans remember, the series takes a group of celebrities — often with eccentric and unique personalities — and sets everyone together in the same house for two weeks of challenges both planned and unforeseen. Similar to shows like CBS' hit Big Brother or MTV's The Real World — which saw its own reboot of sorts this year — the fun is really in seeing how the housemates interact and get along with each other. (Or how they don't.)

The Surreal Life originally ran for six seasons, premiering in 2003 on The WB before eventually moving to VH1. Celebrities from the original run included rapper MC Hammer, former MLB star Jose Canseco and Austin Powers actor Verne Troyer, whose drunken urination on everything in the house quickly became an iconic moment for the series. The Surreal Life reboot is set to premiere on VH1 in the fall, though no specific date has been announced, and the cast boasts the same caliber of celebrities with strong personalities - Dennis Rodman is in the headline, after all - which should make for some pretty entertaining TV. Let's check out the The Surreal Life cast members, and where you've seen them all before.

Dennis Rodman is interviewed on The Last Dance

Dennis Rodman

Dennis Rodman is as much known for his flamboyant personality as he is for his talent on the basketball court. The antics of the NBA bad boy, who has long sported numerous piercings and tattoos along with an ever-changing hair color, was most recently featured on the Chicago Bulls docu-series The Last Dance. Over the years, he also had high-profile romances with Madonna and actress Carmen Electra, and even became a professional wrestler, fighting with the likes of Hulk Hogan and Randy Savage. Possibly the most unexpected of Rodman's actions was the friendship he struck up with North Korean leader Kim Jong-un. Lives don't get much more surreal than Rodman's.

Stormy Daniels is interviewed by Jimmy Kimmel

Stormy Daniels

Adult film star and director Stormy Daniels was in the news a lot a few years ago after accusing former President Donald Trump and his attorney of paying her $130,000 to keep quiet about an affair that allegedly occurred in 2006. Daniels also once considered a run for the U.S. Senate in her home state of Louisiana, as one does, and outside the world of politics, she has made small appearances in the films Knocked Up and The 40-Year-Old Virgin, as well as an episode of Party Down.

August Alsina is interviewed on ET Entertainment Tonight

August Alsina

August Alsina is an R&B artist whose third studio album, The Product III: State of Emergency, was released in 2020. But more so than for his music, Alsina became a household name the same year after he detailed the affair he had with Jada Pinkett Smith. The singer particularly raised eyebrows by saying that Will Smith had given his blessing for the relationship to continue, and while the Smiths at first denied that the "entanglement" occurred, Pinkett Smith later admitted to starting a relationship with Alsina while she and the Fresh Prince were separated. Smith continued to deny that he gave permission, so it's presumed that topic will come up at least once on The Surreal Life.

Tamar Braxton is interviewed on Watch What Happens with Andy Cohen

Tamar Braxton

Tamar Braxton, the R&B singer and younger sister of Toni Braxton, is no stranger to reality TV. She was featured with her sisters on WE's Braxton Family Values, and obviously fronted the spinoff Tamar & Vince. She's also been on RuPaul's Drag Race, Dancing with the Stars (which she had to leave due to health problems) and on Season 2 of Celebrity Big Brother, which led Braxton's former housemate Joey Lawrence to be less than complimentary of the eventual winner. The singer has hit some tough times in the past year, as she addressed an apparent suicide attempt in July 2020, and had a restraining order filed against her by her boyfriend a few months later. But here's hoping that she's feeling better before going into this volcano.

Frankie Muniz is interviewed on Access Hollywood

Frankie Muniz

Frankie Muniz is best known for playing the title role in Malcolm in the Middle, but Muniz has done quite a lot in the 15 years since that series ended. Muniz has competed on Dancing With the Stars and has made guest appearances, often as himself, in shows including Arrested Development and Don't Trust the B---- in Apartment 23, and earned lots of kind words for his killer appearance on The Rookie earlier in 2021. The new dad is also a race car driver, and he's spoken openly about the concussions and mini-strokes he's suffered that have contributed to some pretty severe memory loss.

Kim Coles gives talk show interview

Kim Coles

Kim Coles, who was part of the original cast of the classic sitcom In Living Color, is also joining The Surreal Life cast for its reboot. Coles also played Synclaire James-Jones on Living Single, a series that needs a revival like few others, and recently appeared on an episode of HBO's stellar A Black Lady Sketch Show. The comedian has appeared on the celebrity panels of a number of game shows over the years, including Pyramid, To Tell the Truth and Hollywood Squares. She also has history with VH1, competing on Celebrity Fit Club in 2005.

CJ Perry or Lana WWE talks on her YouTube channel

CJ Perry

CJ Perry is better known to professional wrestling fans as Lana, who was released (in pretty brutal fashion) from the WWE this summer after eight years with the wrestling promotion. But Perry is also a singer and actress who appeared in the movies Pitch Perfect and Pitch Perfect 2. Perry is married to fellow professional wrestler Miro (formerly Rusev in the WWE), who left the WWE for AEW in 2020. She has appeared on the wrestling reality shows Total Divas and Total Bellas, so The Surreal Life should be easy-peasy.

Manny MUA shows off makeup on YouTube channel

Manny MUA

Manny MUA is a makeup artist and beauty blogger who came to fame via his popular YouTube channel. His makeup tutorials led to him becoming the first male brand ambassador for Maybelline, and he now has his own makeup line called Lunar Beauty. I'm particularly excited to see what makeup tips Manny MUA and Dennis Rodman will be exchanging! Manny MUA also recently partnered with President Joe Biden and Anthony Fauci for a town hall to clarify rumors about the COVID vaccinations.

The fun of The Surreal Life's original run came in big part from the wide spectrum of personalities of the celebrities living together, and the chemistry that formed between some of the co-stars led to quite a few spinoff series for VH1. Strange Love starred former housemates Flavor Flav and Brigitte Nielsen, while My Fair Brady gave us a look at the continued relationship between Christopher Knight and Adrianne Curry. What bonds will be formed in the revived version of The Surreal Life, and could they lead to even more reality series? (Say, from Manny and Rodman?) We’ll have to wait and see. In the meantime be sure to check out our 2021 Fall TV schedule to see what else is coming soon.

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Get Involved

Sky Legends, 2002

People’s Artists Fund

Support the PEOPLE’S ARTISTS FUND to keep the arts alive and the voices of artists strong by making a donation to our Monthly Beat Artists Fund.

Become a Sustaining Donor

CIRCA-Pintig has been 100% volunteer-run for most of its existence. All funds raised each year go directly to its programs. Only in the past couple of years has CP started paying staff on a part-time basis. We would like to invite you to be a Sustaining Donor by committing to giving on a sustained basis such as donating $20/month or $1 a day.

With CP’s new direct services programs, sustained funding ensures that CP is able to deliver the services that it planned. Concretely, this means that:

  1. A monthly podcast featuring a story about Asian Americans with disability and their struggles is produced and shared broadly.
  2. At least 1 caregiver story is collected per month, transformed into a monologue and performed in CP’s Monthly Beat event and/or featured in a printed or social media article.

As a Sustaining Donor, you shall enjoy the following benefits:

  • Acknowledgement and listing in a special Sustaining Donors page of the website and in all souvenir playbills.
  • Free admission to all performances and organizational events.
  • Special invitation to Donors-Only private events.
  • Member’s 20% discount for family & friends to all performances and organizational events.
  • Unlimited opportunities to share input and feedback re. CP’s programs
  • A copy of CP’s annual report on the impact of its programs

As a 501(c)3 not-for-profit organization, donations are tax-deductible as fully allowable by law.

Currently all online donations are processed using Network for Good. If you would like to make a donation via mail, you may send a check to “CIRCA Pintig” at 2429 W. Jarvis, Chicago, IL 60645.

The Verdict of the Drawn Circle, 2003

Volunteer, Engage, Take Action

CIRCA-Pintig would love to have you participate in any of its activities and events. Here are a few ways that you can be part of our work:

  • Get trained and conduct interviews and collect stories
  • Be part of playwriting collective that transforms stories into monologues and short performance pieces
  • Assist in developing promotional materials for print and social media
  • Help document activities and community events through photos, videos and voice recordings
  • Translate stories and relevant documents from English to Tagalog and vice-versa
  • Initiate or facilitate community dialogues or conversations with elected officials about specific issues

There is room for everyone. Come on board!

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Some NC teachers concerned about returning to classrooms

Brian Gordon
Asheville Citizen Times
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Second-grade teacher Bailey Hardin prepares paperwork for the upcoming school year on Friday, Aug. 14, 2020, at Rutherfordton Elementary School in Rutherford County, North Carolina. Some North Carolina teachers (but not Hardin) have publicly expressed concern about catching COVID-19 if they have teach in their school buildings instead of from home while teaching online classes.

When more than 1 million North Carolina students resume the school year from home on Monday to avoid COVID-19, many of their teachers will still be at school, and some teachers worry about catching the disease there.

Districts have asked — and in some cases required — teachers to be physically present at schools when classes start. This includes many of the more than 60 districts starting under remote instruction to deter the spread of the coronavirus.

School district leaders said the policy promotes consistency for students.

Some educators argue against the policy. They said it shows a lack of trust in them and forces teachers to weigh job security against health risks.

“When it comes down to it, teachers are professionals that can be trusted to do that job effectively and consistently, even from home,” said Paula Dinga, a third-grade teacher in Buncombe County Schools and president of the Buncombe County Association of Educators.

Paula Dinga, a third-grade teacher and president of the Buncombe County Association of Educators.

After COVID-19 concerns closed school buildings in March, North Carolina teachers concluded the school year from home. They relied heavily on virtual platforms like Google Classroom and Canvas, as well as physical take-home packets, to teach from afar.

As thousands of teachers reentered buildings this week to prepare for the school year, districts implemented safety protocols like temperature checks, mask mandates and enhanced cleanings. Despite these precautions, some teachers said being at school will change how they conduct their lives outside of work.

More:Pandemic pods and private schools: NC parents scramble for solutions as school year nears

'They don’t want to rock the boat'

After returning to her school, Tara O’Loughlin, who teaches art in Haywood County Schools, stopped seeing her father because he was recently diagnosed with cancer. The Centers for Disease Control and Prevention says cancer patients, particularly ones whose immune systems have been suppressed by chemotherapy, have an increased fatality risk if they contract COVID-19.

“I would be apprehensive to help out with family stuff,” said O’Loughlin, who also serves as president of the Haywood County Association of Educators. “Even though the kids aren’t there, it’s still like 60-plus teachers that are in a school, with oftentimes antiquated ventilation systems.”

As is typical in other districts, Haywood County allows teachers to request exceptions from teaching in buildings, with accommodations for medical or personal reasons decided on a case-by-case basis. O’Loughlin said her principal is willing to work with her so she can care for her father.

She hoped the district would in general allow teachers to work from home and arrange for those who need to work from school to do so.

Teacher assistant Anthony Purcell passes a laptop and other school items to a parent at W.H. Owen Elementary School in Fayetteville on Tuesday. While students will study from home because of COVID-19, many teachers in North Carolina will be required to conduct the online lessons from their classrooms, and they worry about catching the disease at work.

“If there were teachers that maybe did have (internet) connection issues or needed more accountability, I would love that they be brought in on a person-to-person basis rather than staff at a whole,” O’Loughlin said.

Loughlin and Dinga said they know co-workers who are afraid to request exceptions, even if health conditions leave them more vulnerable to COVID-19 symptoms.

“It just makes me sad to see people putting themselves at risk because they don’t want to rock the boat,” Loughlin said.

Tamika Walker Kelly is president of the North Carolina Association of Educators, the largest teacher advocacy organization in the state. She said a mandate to have staff physically be in buildings, “feels troubling, especially when it is framed in the manner of professionalism.”

“Professionalism doesn’t limit itself to being physically present in a building and this requirement undermines the relationship of trust between educators and school districts,” she said.

More:Most NC students will start new year outside of school. See districts' plans.

'I'm torn': Asheville, Buncombe parents brace for remote school reopening plans

Districts say location matters

District representatives said there are advantages to having teachers back in the buildings. For example, they said certain courses like chemistry benefit from having teachers in labs.

“The physical classroom best models the learning environment that students will return to,” wrote Scott Rhodes, chief human resources officer at Henderson County Public Schools. “Additionally, the internet bandwidth and instructional materials on hand in a school environment ensure teachers have access to the resources needed for highly-engaged student learning.”

Alamance-Burlington School System Public Information Officer Jenny Faulkner wrote that “having staff in buildings will help us develop routines and guidelines that will be effective when students begin to return.”

The district thinks students will be more comfortable returning to classrooms if they regularly see their classrooms beforehand, Faulkner said, even if it’s through a screen. The Alamance-Burlington schools offer flexible work placements at the start of the year for staff managing child care or family and personal health concerns, he said.

Hendersonville Elementary School at 1039 Randall Circle in Hendersonville as it appeared Thursday, Oct. 31, 2019.

Parent and staff surveys at Asheville City Schools showed students were “more engaged when they are receiving whole class sessions from a classroom setting,” said district spokesperson Ashley-Michelle Thublin.

And in the surrounding Buncombe County Schools, associate superintendent Susanne Swanger said coming to school will help educators both better access resources and collaborate with co-workers in small professional learning communities.

Cumberland County Schools encourages staff to physically report to their work locations, but Carol Stubbs, president of the Cumberland County Association of Educators, doesn’t sense her fellow educators feel overly pressured to show up if it’s not best for them.

“Those who want to stay home stay home,” she said. “And a lot of them want to (come to school buildings) because they can get more done.”

Teacher Angie Cathcart of Asheville Middle School.

Some educators disagree that lessons from school enhance the learning students will get through their computer screens.

“With the way our platforms are designed and the digital tools that our teachers are using, I don’t see much difference,” said Angie Cathcart, a digital lead teacher at Asheville Middle School.

Brian Gordon is the education and social issues reporter for the USA Today Network in North Carolina. Reach him at or follow him on Twitter @briansamuel92.

Keep local journalism possible with a subscription to the Citizen-Times.

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How Citrix can help SMBs overcome disruptions to their business

Providing a seamless transition to remote work

In this video testimonial, learn about how Nick Casagrande, IT Director at LGL, relied on Citrix Virtual Apps and Desktops and Content Collaboration to keep his company connected while shifting to remote work.

Despite not being able to meet or talk in person like his company was used to, their transition was seamless. Citrix helped them easily provision desktops and enable collaboration from anywhere.

Watch now to learn more.

Nick Casagrande
IT Director

Complete the form to view this customer testimonial video.


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Infographic: Building the digital workplace

What comes next in the mobile revolution

A recent study by Oxford Economics and Citrix reveals that digital workplace strategies drive improved performance. However, most organizations still need to update their strategies and practices—few have done enough to change technology, policies, or culture to capitalize on these transformational developments.


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Sign Ordinance

The City of Pacifica's sign ordinance requires issuance of a sign permit for all new permanent signs. New businesses are particularly affected by the ordinance because all new signs are subject to the regulations.

All new permanent signs are required to receive an administrative sign permit from the Pacifica Planning Department. Temporary advertising signs are allowed without a sign permit provided that they are installed on the interior side of a window only. For more information on the permitted sign area for both permanent and temporary signs, please refer to the sign ordinance or speak to a city planner.

Specific regulations apply to businesses that are located in a multi-unit development (defined as a building or group of buildings comprising two or more businesses that are planned, developed or owned and managed as a unit). In an effort to achieve uniform and consistent signage for multi-unit developments, the city requires preparation of a master sign program for the entire complex when a new sign is proposed. The owner of the multi-unit development of the person proposing the new business would be responsible for developing the sign program and for installing the approved sign for the new business. As other businesses in the multi-unit development change or as existing signs meet the criteria contained in the "Nonconforming Signs" section of the ordinance, they will be required to be brought into conformance with the master sign program.

Finally, it should be noted that banners, pennants and other similar temporary signage placed on the exterior of a building are generally prohibited, although they may be permitted at the opening of a new business or for special events with prior approval of the planning director. In such case, the banners or pennants may be displayed only for 30 days.

Please visit the planning department at 1800 Francisco Boulevard or call 650-738-7341 to apply for a sign permit or to get more information about the sign ordinance.